Are you listening to your Skype call on the same audio device that you have selected in OBS? You have speakers selected to "pull" audio from so anything not playing on speakers won't be captured
Skype doesn't change it's audio playback device when you change your default in windows. Sometimes Skype will even use 2 playback devices, one for the "ringing" and another for the call audio. The extent of what I can recommended is check which audio device Skype is using for call audio and match it on OBS.
If it's anything else then it's out of my area of solvability.
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