Once I get back in town, I would love to stop by the chat. As it is, unfortunately, I'm going out of town tonight and wont' be back until Sunday.
As I said, until the most recent update, I had the opposite problem I'm having now. You'll see in my VODs I've already posted in this thread where my desktop AV is synced fine, but my webcam video is ahead of my Mic audio. This was with version 0.448a.
Now in this new VOD:
http://www.twitch.tv/scxerouz/b/345901403 (version 0.452a) you can see from the get go that my audio is now a full 2 seconds or so ahead of all video (webcam and desktop). It's hard to tell, but game sounds are ahead too. I haven't tried the audio sync fix yet, as I didn't notice this problem until I looked at my VOD this morning.
I don't know if these VODs help at all with what you're doing. I'd love to be able to help you test it out, and if you still need me to stop by chat on Sunday, I surely will.