Potential solution pending tomorrows stream :P
(TLDR : OBS and Device power consumption = more than laptop charger provide. So power USB hubs and devices separately with device linked bellow.)
OK so after a bit of troubleshooting, I realised the devices plugged in (Brio Webcam, Mic and Elgato HD60s+) where drawing enough watts in combination with OBS's power consumption (which seems to be higher for me since 28. released) to stray over the 94 watts the laptop charger can supply. Hence it starts scavenging power from the battery.
To combat this I have plugged the USB hub with my mic and webcam in with a 20 watt apple charger to provide power for those two devices and the hub itself which is doing the ethernet also, the hubs pass-through power port will power the hub and devices and Apples website confirmed that the laptop will look for the port providing the most power and ignore other powered connections. This should be sufficient based on my guestimate that each USB device is drawing 900ma at 5v and the hub itself handling data and ethernet would draw something similar. This resulted in the power draw on the battery being less whilst streaming, which seems to confirm my theory.
However there was still draw on the battery due to the capture device, which means I couldn't do special event streams lasting longer than 8-9 hours, and I still feel that using battery power in conjunction with the power from the wall is cycling the battery and not good for it's lifespan or performance. So for the capture device which is the other side of the room I have purchased and active USB extension :
and a USB to barrel jack cable for its power :
This setup seems to provide three advantages ;
The capture card is powered even when its not plugged into the laptop, so on non-stream days the passthrough of the capture card works fine. So I can game normally without needing a spare USB power source for the capture card.
This also powers the device when its plugged into the laptop which should stop power draw. This means I should only need to power the laptop itself to run OBS and encode and upload my stream. I cant see any way that OBS could be using more than the 94 watts the laptop charger provides.
The extender comes with a VERY long cable which can be handy for setups like mine where the console and TV and capture device are the other side of the room. This active extension both powers the device and provides a cable long enough to reach where my laptop is when I stream. Which is great as a decent length USB C to C had its own cost which can be avoided with this device.
So as mentioned I will be streaming tomorrow to test this setup and will aim to update if there are any issues.