Question / Help Is there a way to keep one window shown recording while have multiple windows up

Just use window capture for chrome. With your current version of windows, you will need to disable hardware acceleration in chrome.

If you update windows, OBS can use the 1909 version window capture method which works even with hardware acceleration enabled.
 
For that, make a Display Capture source, and crop it down to the area you want by holding alt and dragging the bounding box.
 
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