First, to reset any accidental scaling/fitting/stretching, right-click your capture device source->Transform->Reset transform.
Then, to adapt your canvas and output resolution to that of the capture device, right-click your capture device source->reseize output (source size).
This way your canvas and output size is the same resolution as your capture device, so your video will contain 1:1 every pixel from what the capture device will capture, unrescaled, undistorted.