You can click into the fields and enter any value. The resolution values from the dropdown list are only proposals with common resolutions.
You can also right-click your capture device source in OBS while the source is showing some preview -> resize output (source size) to set canvas and output resolution to exactly the size of the source.
With the fps, look what the capture card will provide. Copy this value to OBS. This is something you have to read from the capture card. In your log, it was exactly 25 fps:
10:15:30.879: [DShow Device: 'Video Capture Device'] settings updated:
10:15:30.879: video device: AV TO USB2.0
10:15:30.879: video path: \\?\usb#vid_534d&pid_0021&mi_00#6&6af79c6&0&0000#{65e8773d-8f56-11d0-a3b9-00a0c9223196}\global
10:15:30.879: resolution: 640x480
10:15:30.879: fps: 25.00 (interval: 400000)
10:15:30.879: format: MJPEG
If your tape material is NTSC, then you should change the settings in the properties of the capture card to match the fps of your material. For NTSC, it may be 29.97 or 24 NTSC, depending on the tape and on the tape recorder. I'm not that familiar with NTSC, I would try 29.97 first, since the Wikipedia article about VHS says there are 60 half frames are recorded, thus 30 fps - and as far as I know this is actually 59.94/29.97.
If you capture or record with mismatching fps, you might perceive stutters in your recorded video. You should match the fps of the original material with both the capture card and OBS.