Deinterlacing is available for several source types in the context menu of that source. Media Sources and Video Capture Sources have these.
Downscaling might be an idea. capture at 720x576 and downscale to 320x240.
For a start, I propose you capture at 720x576 and save exactly this resolution, then downscale in a postprocessing step.
Use simple output mode and not ffmpeg custom output. Choose "Indistinguishable Quality, Large File Size" as output quality and mkv as Recording format. This is going to be your raw recording and you can feed this into the postprocessing software of your choice. Record one without deinterlacing and deinterlace during postprocessing, and one with some deinterlacing.
If you mangle your source during recording too much, you are unable to correct any handling errors later. You will make many errors and you will learn how to produce better video with the right postprocessing, if you do much trial and error. It is much easier to postprocess a raw video without any mangling than to rewind and re-record the tape constantly for every new iteration.
Unfortunately, this is a very old task and much knowledge is lost. Digitizing analog material was done primarily 10-15 years ago. You might find more stuff on the net if you google for this topic.
Visit the
virtualdub website and get
virtualdub for postprocessing. It's somewhat old software, but it contains many filters for postprocessing digitized analog video. It may be difficult to feed OBS-recorded video to virtualdub, because virtualdub neither supports any of the native container formats of OBS, only *.avi, and it doesn't support x.264.